Photocatalytic Activity of Combustion Synthesized Nanocrystalline CeAlO3     

Parag A. Deshpande  S. T. Aruna  Giridhar Madras 《洁净——土壤、空气、水》2011,39(3):259-264

The photocatalytic activity of combustion synthesized nanocrystalline CeAlO₃ was determined for the degradation of four anionic and four cationic dyes. The perovskite oxide showed high‐photocatalytic activity and a complete degradation of all the dyes was possible within 2 h. The photocatalytic activity of the compound was comparable with the activity of the commercial Degussa P‐25 TiO₂ catalyst. The degradation of dyes was found to follow first order kinetics and the first order degradation rate constants were determined.  相似文献   

Plant Species Mediate Rhizosphere Microbial Activity and Biodegradation Dynamics in a Riparian Soil Treated with Bensulfuron‐methyl     

Changming Yang  Yulai Wang  Jianhua Li 《洁净——土壤、空气、水》2011,39(4):338-344

A pot experiment was conducted to investigate microbial characteristics and the biodegradation process of bensulfuron‐methyl (BSM) in a rhizosphere soils planted with different riparian plants. The results showed that microbial population decreased with BSM addition in the rhizosphere, especially for bacteria and fungi. The activities of the dehydrogenase (DHase) were stimulated firstly, due to BSM addition, but then were inhibited, and recovered to the initial level, while the activities of the phosphatase and urease showed obviously decreasing trend throughout the whole experiment. Rhizosphere soil substrate‐induced respiration (SIR) was depressed by BSM, especially at the initial 14 days of incubation. Compared to Zizania aquatica and Phragmites australis, Acorus calamus showed a significantly (p < 0.05) higher DHase activity and larger SIR in the rhizosphere soils treated with BSM, which means that A. calamus can effectively alleviate inhibitory effect of the sulfonylurea herbicide addition on microbial activity. There were significant (p < 0.05) differences in microbial degradation dynamics of BSM in the rhizosphere soils among three kinds of riparian plants. A. calamus displayed a significantly (p < 0.05) higher degradation efficiency of BSM in the rhizosphere soils, followed by Z. aquatica and P. australis. The residual BSM concentration in A. calamus rhizosphere soil was 23.1 and 32.2% lower than that in Z. aquatica and P. australis rhizosphere soils, respectively, indicating a greater improvement effect on biodegradation of BSM in A. calamus rhizosphere soils.  相似文献   

中国南方湿润区“荒漠化”问题讨论   总被引：2，自引：0，他引：2  

金远亮  彭华  闫罗彬  项跃武  王翔宇 《地理科学进展》2015,34(6)

荒漠化是当今世界所面临的严重的环境与社会经济问题,推进荒漠化研究工作对于保护生态环境,促进区域可持续发展具有重要意义。本文在对荒漠化内涵进行系统回顾的基础上,认为除了人为干扰叠加气候性干旱作用导致的荒漠化之外,南方湿润区因水土流失叠加物理性干旱作用导致的极端土地退化也是一种荒漠化,并从物质基础、气候条件、影响因子、形成营力、核心作用和地表过程方面进行比较,最后以南方红层区特殊的"红层荒漠化"为案例,利用实地调查和TM影像的植被覆盖度指标VFC对1992-2013年红层土地退化进行分析。结果显示,在人为反复干扰和其他自然因素作用下地表植被持续退化、群落干旱趋势明显,表土层流失,岩石风化加剧,以致形成类似"荒漠"景观的现象。红层区的退化过程可类比于喀斯特石漠化、红壤山地丘陵退化,但这类极端土地退化现象可否视为"荒漠化",有待于进一步的深入研究。  相似文献   

Land desertification and restoration in Middle East and North Africa (MENA) region     

Hassan M. El Shaer 《寒旱区科学》2015,7(1):0007-0015

The Middle East and North Africa (MENA) region is characterized by high population growth, degraded and fragile nat-ural ecosystems, and a limited amount of arable lands. It is one of the most water-sc...  相似文献   

石灰土中秸秆还田降解率及其对土壤肥力的影响   总被引：1，自引：0，他引：1  

黄芬  韦红群  曹建华 《资源与生态学报(英文版)》2015,(4)

石灰土具有高的有机碳的积累,但营养成分的供给速率偏低,导致土壤贫瘠。本文通过室内模拟实验,研究相同来源玉米秸秆在岩溶土与非岩溶土中的降解情况,对秸秆降解率、土壤理化性质、土壤肥力等进行动态检测,结果表明：（1）总体上岩溶土秸秆降解速率比非岩溶土快。秸秆降解速度最快主要集中在最初60天,之后呈缓慢上升趋势,到98天基本达到平衡。非岩溶土降解峰值出现时间为第42天,岩溶土为第28天,峰值出现时间前者比后者滞后14天。总降解时间持续160天,岩溶土降解率为77%,非岩溶土为75%。（2）秸秆降解期间,土壤pH值前期有下降的趋势,后期慢慢回升,这与秸秆降解过程中不同时期降解产物变化规律相吻合。秸秆还田可以提高土壤肥力,其中速效氮和速效钾含量增加非常明显。（3）与岩溶土相比,全量检测结果显示各肥力指标在非岩溶土含量低,但升幅百分比高;有效态检测结果显示非岩溶土速效磷和速效钾含量高。说明秸秆还田一些营养元素有效态在非岩溶土中更易于释放,而岩溶土由于其土壤质地的特殊性,许多养分被土壤粘土矿物牢固结合,营养元素供给速率慢,但因此也易于养分全量的累积。  相似文献   

Mapping degraded grassland on the Eastern Tibetan Plateau with multi-temporal Landsat 8 data — where do the severely degraded areas occur?     

《International Journal of Applied Earth Observation and Geoinformation》2015

The Tibetan Plateau in Western China is the world’s largest alpine landscape, sheltering a rich diversity of native flora and fauna. In the past few decades, the Tibetan Plateau was found to suffer from grassland degradation processes. Grassland degradation is assumed to not only endanger biodiversity but also to increase the risk for natural hazards in other parts of the country which are ecologically and hydrologically connected to the area. However, the mechanisms behind the degradation processes remain poorly understood due to scarce baseline data and insufficient scientific research.We argue that remote sensing data can help to better understand degradation processes and patterns by: (1) identifying the distribution of severely degraded areas and (2) comparing the patterns of key spatial attributes of the identified areas (altitude above sea level, aspect, slope, administrative districts) with existing theories on degradation drivers. Therefore, we applied four Landsat 8 images covering large portions of the three counties Jigzhi, Baima and Darlag in the Eastern Tibetan Plateau. The dates of the Landsat scenes were selected to cover differing phenological stages of the ecosystem. Reference data were collected with a remotely piloted aircraft and a standard consumer RGB camera. To exploit the phenological information in the Landsat data as well as deal with the problem of cloud cover in multiple images, we developed a straightforward PCA-based procedure to merge the Landsat scenes. The merged Landsat data served as input to a supervised support vector machine classification which was validated with an iterative bootstrap procedure and an additional independent validation set. The considered classes were “high-cover grassland”, “grassland (including several stages of grassland vitality)”, “(severely) degraded grassland”, “green shrubland”, “grey shrubland”, “urban areas” and “water bodies”. Kappa accuracies ranged between 0.84 and 0.93 in the iterative procedure, while the independent validation led to a kappa accuracy of 0.76. Mean producer’s and user’s accuracies for all classes were higher than 80%, and confusion mainly occurred between the two shrubland classes and between the three grassland classes.Analysis of the slope, aspect and altitude values of the vegetation classes revealed that the degraded areas mostly occurred at the higher altitudes of the study area (4300–4600 m), with no strong connection to any specific slope or aspect. High-cover grassland was mostly located on sunny slopes at lower altitudes (less than 4300 m), while shrubland preferred shady, relatively steep slopes across all altitudes. These observations proved to be stable across the examined counties, while the proportions of land-cover classes differed between the examined regions. Most counties showed 5–7% severely degraded land cover. Darlag, the county located at the edge of the permafrost zone, and featuring the highest average altitude and lowest annual temperature and precipitation, was found to suffer from larger areas of severe degradation (14%).Therefore, our findings support a strong connection between degradation patterns and climatic as well as altitudinal gradients, with an increased degradation risk for high altitude areas and areas in colder and drier climatic zones. This is relevant information for pastoral management to avoid further degradation of high altitude pastures.  相似文献   

长江口外浮游植物死亡释放溶解有机质的降解及其溶氧消耗   总被引：2，自引：0，他引：2  

高小丰  吴莹  朱卓毅 《海洋与湖沼》2015,46(5):1010-1017

浮游植物光合作用产生的溶解有机质(dissolved organic matter,DOM)是海洋中溶解有机质的重要来源,浮游植物死亡后释放的新鲜溶解有机质活性高、数量大、生物可利用性高,其降解过程中对溶解氧(dissolved oxygen,DO)的消耗显著。但到目前为止,对此类溶解有机质的降解过程以及其耗氧情况还鲜有研究。本文基于2013年8月东海航次,对浮游植物(硅藻为主)死亡后释放的新鲜有机质进行人工受控培养,研究其降解过程及对DO的消耗,并评估该降解过程对低氧现象形成的贡献。研究发现:培养体系中溶解有机碳(dissolved organic carbon,DOC)和DO浓度皆随时间呈指数下降,总溶解态碳水化合物(total carbohydrate,TCHO)也出现明显降解;体系的初始DOC浓度越高,降解速率常数k(DOC)、k(DO)越大,k(DOC)受DOC浓度、活性以及DO浓度的影响;培养过程中细菌丰度明显增加,添加Hg Cl2的对比实验表明细菌在降解过程中起到重要作用。本文的研究结果表明,浮游植物死亡后释放的溶解有机质的快速降解及其对溶解氧的消耗,对长江口低氧环境的促成具有重要意义。  相似文献   

黄渤海海水中丙烯酸的生成与降解的初步研究     

刘欢欢  刘春颖 《海洋与湖沼》2015,46(2)

在黄渤海海域对β-二甲基巯基丙酸内盐（DMSP）降解产生丙烯酸和丙烯酸的降解过程做了初步研究。结果表明,海水中有明显的DMSP降解和丙烯酸的生成现象。在DMSP降解初期,DMSP不断降解,丙烯酸则在经过1 h后浓度开始上升,达到最大值后再次下降。起始DMSP浓度越高,降解得越完全,且丙烯酸最大值越大。在观测的5 h内,丙烯酸的表观降解速率总是大于DMSP的表观降解速率,且两者都与初始浓度成正相关。在丙烯酸的降解过程中,黑暗条件下起始浓度越大,丙烯酸变化速率越大,而光照条件下则恰好相反。光化学反应中前2 h表现为丙烯酸的光化学生成,而后2 h表现为光化学降解。  相似文献   

基于生态系统的上海崇明东滩海岸带生态系统退化诊断   总被引：1，自引：0，他引：1  

袁琳  张利权  翁骏超  葛振鸣 《海洋与湖沼》2015,46(1):109-117

海岸带是资源与环境条件最为优越的区域,也是与人类发展关系最为密切的区域之一。本文选择上海崇明东滩海岸带生态系统为研究示范区,在对崇明东滩海岸带生态系统结构分析的基础上,基于"压力-状态-响应"模型构建海岸带生态系统退化诊断指标体系,定量评估了崇明东滩海岸带生态系统退化状况。结果表明,从2000年至2008年,崇明东滩海岸带生态系统整体上表现为健康,局部区域表现为轻微退化,轻微退化的面积分别为25.71km2(2000)、16.66km2(2003)、18.16km2(2005)和40.46km2(2008)。自然湿地生态系统是崇明东滩海岸带中一个重要的生态系统类型,2000年至2008年,崇明东滩自然湿地生态系统大部分面积保持在健康的状态,大规模的围垦工程和外来物种互花米草入侵是造成自然湿地生态系统退化的主要原因。2000年至2008年,崇明东滩农业生态系统整体上表现为健康状态,产业结构不合理和由于化肥、农药使用造成的环境恶化等问题,是造成崇明东滩海岸带农业生态系统局部区域发生退化的主要原因。人口增长和经济发展引起的现有资源的过度使用和环境恶化等问题,使得城镇生态系统健康面临巨大挑战,在2005年表现为轻微退化。本文的研究方法可为我国其它地区海岸带生态系统管理和建设提供理论依据和示范案例。  相似文献   

碳纳米管和纳米二氧化钛复合光催化剂处理海洋柴油污染的研究     

吴云英  于晓彩  金晓杰  尹丹妮  尚晓琳  薛冠华 《海洋技术学报》2015,34(5):104-108

利用溶胶凝胶法自制了碳纳米管和纳米二氧化钛的复合光催化剂,采用投射电子显微镜和X光衍射仪对粉体的粒径、物象、形貌和热稳定性等进行表征。通过研究光照条件、催化剂的投加量、油的初始浓度、催化剂制备的煅烧条件等因素,考察了自制碳纳米管和纳米二氧化钛的复合催化剂对降解模拟海洋柴油污染的海水去除率的影响。研究发现,在可见光照条件下,400℃煅烧2 h的复合催化剂,投加量为0.4 g/L、柴油的初始浓度为0.6 g/L、反应的光照时间为4 h时效果最好,去除率可达到67.65%。  相似文献